energyЭнергетика. Известия высших учебных заведений и энергетических объединений СНГENERGETIKA. Proceedings of CIS higher education institutions and power engineering associations1029-74482414-0341BNTU10.21122/1029-7448-2025-68-4-353-366energy-2482Research ArticleТЕПЛОЭНЕРГЕТИКАНEAT POWER ENGINEERINGРазработка и исследование адсорбентов сероводорода из природных материаловDevelopment and Investigation of Hydrogen Sulfide Adsorbents From Natural MaterialsФилимоноваА. А.FilimonovaA. A.

Казань, Российская Федерация

Kazan, Russian Federation

vlasovaay@mail.ruВласоваА. Ю.VlasovaA. Yu.

Адрес для переписки:Власова Алена Юрьевна -Казанский государственный  энергетический университет,ул. Красносельская, 51, 420066, г. Казань, Российская Федерация.Тел.: +7 843 519-42-52  vlasovaay@mail.ru 

 

Address for correspondence:Vlasova Alena Yu. Kazan State Power  Engineering University,  51, Krasnoselskaya str.,  420066, Kazan, Russian Federation.Tel.: +7 843 519-42-52 vlasovaay@mail.ru  

 

vlasovaay@mail.ruЧичироваН. Д.ChichirovaN. D.

Казань, Российская Федерация

Kazan, Russian Federation

vlasovaay@mail.ruКамалиеваР. Ф.KamalievaR. F.

Казань, Российская Федерация

Kazan, Russian Federation

vlasovaay@mail.ruКарницкийН. Б.KarnitskyN. B.

Минск, Республика Беларусь

Minsk, Republic of Belarus

vlasovaay@mail.ruКазанский государственный энергетический университетРоссияKazan State Power Engineering UniversityRussian FederationБелорусский национальный технический университетБеларусьBelarusian National Technical UniversityBelarus202513082025684353366Copyright © Филимонова А.А., Власова А.Ю., Чичирова Н.Д., Камалиева Р.Ф., Карницкий Н.Б., 20252025Филимонова А.А., Власова А.Ю., Чичирова Н.Д., Камалиева Р.Ф., Карницкий Н.Б.Filimonova A.A., Vlasova A.Y., Chichirova N.D., Kamalieva R.F., Karnitsky N.B.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://energy.bntu.by/jour/article/view/2482

Адсорбционные материалы на основе природных минералов рассматриваются в мировой литературе как недорогие адсорбенты сероводорода, способные полностью заменить коммерческие продукты, такие как синтетические цеолиты. Мировой спрос на недорогие, доступные, безопасные материалы растет, в том числе в сфере очистки промышленных и сельскохозяйственных газовых выбросов от сероводорода. В статье представлен анализ литературных данных о природных глинах, активном иле и других материалах и способах их использования для адсорбции сероводорода. Приведены данные о составах активного ила, глин и известняковых пород, исследования которых проведены на инфракрасном спектрофотометре. Неорганическая составляющая активного ила включает в себя оксид железа, соединения алюминия, кальция, магния, силикаты. Горная известковая порода состоит из карбонатов, оксида железа, силикатов, при прокаливании при высоких температурах образует преимущественно оксид кальция. Различные глины содержат алюмосиликаты, оксиды железа, меди, кобальта, марганца. За счет содержания оксидов металлов природные материалы имеют механизм хемосорбции, а за счет содержания соединений алюминия и кремния обладают физическим механизмом сорбции. Разработаны 17 составов композиционных материалов из природных минералов и изучено их содержание серы. Также было проведено исследование поглощающей способности активного ила в жидком состоянии. Показано, что все природные материалы обладают высоким потенциалом для использования в качестве адсорбентов при минимальной подготовке (обезвоживании, прокаливании). Композиции, не содержащие дорогостоящих добавок, состоящие в основном из обожженной известняковой породы и глин, показали сероемкость от 10 до 40 %.

Adsorption materials based on natural minerals are considered in the world literature as inexpensive hydrogen sulfide adsorbents capable of completely replacing commercial products such as synthetic zeolites. The global demand for inexpensive, accessible, safe materials is growing, including in the field of cleaning industrial and agricultural gas emissions from hydrogen sulfide. The article presents an analysis of literary data on natural clays, activated sludge and other materials and methods of their use for hydrogen sulfide adsorption. Data on the composition of activated sludge, clays and limestone rocks are provided. The composition studies were carried out on an infrared spectrophotometer. The inorganic component of activated sludge includes iron oxide, aluminum, calcium, magnesium compounds, and silicates. Limestone consists of carbonates, iron oxide, silicates, and when calcined at high temperatures, it mainly forms calcium oxide. Various clays contain aluminosilicates, iron oxides, copper, cobalt, and manganese. Due to the content of metal oxides, natural materials have a chemisorption mechanism, and due to the content of aluminum and silicon compounds, they have a physical sorption mechanism. 17 compositions of composite materials from natural minerals were developed and their sulfur content was studied. A study was also conducted on the absorption capacity of activated sludge in a liquid state. It was shown that all natural materials have a high potential for use as adsorbents with minimal preparation (dehydration, calcination). Compositions that do not contain expensive additives, consisting mainly of сalcined limestone rock and clays, showed sulfur capacity from 10 to 40 %.

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The authors declare that there are no conflicts of interest present.